2,2,2-Trimethyl-N-(phenyl­sulfon­yl)­acetamide

نویسندگان

  • B. Thimme Gowda
  • Sabine Foro
  • B. P. Sowmya
  • P. G. Nirmala
  • Hartmut Fuess
چکیده

The N-H and C=O bonds of the SO(2)-NH-CO group in the title compound, C(11)H(15)NO(3)S, are anti to each other. The asymmetric unit contains two independent mol-ecules. The benzene rings form dihedral angles of 83.19 (8) and 76.01 (10)° with the mean planes of the C(2)NOS fragments. The mol-ecules are linked into chains parallel to the b axis by inter-molecular N-H⋯O hydrogen bonds.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

N-(4-Chloro­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide

In the crystal structure of the title compound (N4CPSTMAA), C(11)H(14)ClNO(3)S, the conformations of the N-H and C=O bonds in the amide group are anti to each other, similar to those observed in N-phenyl-sulfonyl-2,2,2-trimethyl-acetamide (NPSTMAA) and 2,2,2-trimethyl-N-(4-methyl-phenyl-sulfon-yl)acetamide (N4MPSTMAA). The bond parameters in N4CPSTMAA are similar to those in NPSTMAA, N4MPSTMAA,...

متن کامل

2,2-Dichloro-N-(4-methyl­phenyl­sulfonyl)acetamide

The N-H and C=O bonds in the title compound, C(9)H(9)Cl(2)NO(3)S, are trans to each other, similar to what is observed in 2,2,2-trimethyl-N-(phenyl-sulfon-yl)acetamide and 2,2,2-trimethyl-N-(4-methyl-phenyl-sulfon-yl)acetamide. The bond parameters in the title compound are also similar to those in the aforementioned two structures. N-H⋯O hydrogen bonds connect the mol-ecules into chains running...

متن کامل

N-(2,6-Dimethyl­phen­yl)-2-methyl­acetamide

The structure of the title compound (26DMPMA), C(11)H(15)NO, is closely related to the side-chain unsubstituted N-(2,6-dimethyl-phen-yl)acetamide and side-chain substituted N-(2,6-dimethyl-phen-yl)-2,2,2-trimethyl-acetamide and 2-chloro-N-(2,6-dimethyl-phen-yl)acetamide, with slightly different bond parameters. The mol-ecules in 26DMPMA are linked into chains through N-H⋯O hydrogen bonding.

متن کامل

N-(4-Bromo­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide

The conformations of the N-H and C=O bonds in the SO(2)-NH-CO-C group of the title compound (N4BPSTMAA), C(11)H(14)BrNO(3)S, are trans to each other, similar to what is observed in N-(4-chloro-phenyl-sulfon-yl)-2,2,2-trimethyl-acet-amide (N4CPSTMAA) and 2,2,2-trimethyl-N-(4-methyl-phenyl--sulfon-yl)acetamide (N4MPSTMAA). The bond para-meters in N4BPSTMAA are similar to those in N4CPSTMAA, N4MPS...

متن کامل

2,2-Dichloro-N-(4-chloro­phenyl­sulfon­yl)­acetamide

In the crystal structure of the title compound (N4CPSDCAA), C(8)H(6)Cl(3)NO(3)S, the conformations of the N-H and C=O bonds in the SO(2)-NH-CO-C group are trans to each other, similar to those observed in 2,2-dichloro-N-(phenyl-sulfon-yl)-acetamide (NPSDCAA), 2,2-dichloro-N-(4-methyl-phenyl-sulfon-yl)acetamide (N4MPSDCAA) and N-(4-chloro-phenyl-sulfon-yl)-2,2,2-trimethyl-acetamide (N4CPSTMAA), ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008